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41225 Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane (1:1), Pd 13%

CAS Number
95464-05-4
Synonyms
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride
PdCl2(dppf)•CH2Cl2

Stock No. Size Price ($) Quantity Availability
41225-03 1g 47.70
41225-06 5g 142.00
41225-14 25g 664.00
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Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane (1:1), Pd 13%

MDL
MFCD00792899

Chemical Properties

Formula
C34H28Cl2FeP2Pd.CH2Cl2
Formula Weight
816.64
Form
Powder
Melting point
275-280°
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) is used for palladium-catalyzed coupling reactions. It serves as a catalyst and also employed in carbonylation reactions. Further, it is used in cross-coupling reaction and Suzuki reaction.

Notes

Incompatible with strong oxidizing agents.

Literature References

Hagihara, R.; Harada, N.; Karasawa, S.; Koga, N. Crystalline transformations of dinaphthyridinylamine derivatives with alteration of solid-state emission in response to external stimuli. CrystEngComm 2015, 17 (46), 8825-8834.

Lu, Q.; Li, X.; Li, J.; Yang, Z.; Xu, B.; Chi, Z.; Xu, J.; Zhang, Y. Influence of cyano groups on the properties of piezofluorochromic aggregation-induced emission enhancement compounds derived from tetraphenylvinyl-capped ethane. J. Mater. Chem. C 2015, 3 (6), 1225-1234.

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H312+H332-H315-H319-H335

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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