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41684 Triisopropylphosphine, 98%

CAS Number
6476-36-4
Synonyms

Stock No. Size Price ($) Quantity Availability
41684-04 2g 125.00
41684-09 10g 523.00
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Triisopropylphosphine, 98%

MDL
MFCD00015029
EINECS
229-333-1

Chemical Properties

Formula
[(CH3)2CH]3P
Formula Weight
160.24
Form
Liquid
Boiling Point
176-178°
Flash Point
-17°(1°F)
Density
0.839
Refractive Index
1.4670
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Soluble in alkanes.

Applications

Triisopropylphosphine is used as a ligand in organometallic chemistry. It is also used to produce chlor(triisopropyl)phosphonium- dimesylamid at temperature of 40°C.

Notes

Air sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Literature References

T. Yoshida.; David L. Thorn.; T. Okano.; Sei Otsuka.; James A. Ibers. Dynamic properties of phosphinehydridorhodium(I) complexes and the structure of tris(triisopropylphosphine)hydridorhodium(I), RhH(P(i-Pr)3)3.J. Am. Chem. Soc.1980,102(21), 6451-6457.

M.A. Esteruelas; H. Werner. Five- and six-coordinate hydrido(carbonyl)-ruthenium(II) and -osmium(II) complexes containing triisopropylphosphine as ligand.Journal of Organometallic Chemistry. 1986,303(2), 221-231.

GHS Hazard and Precautionary Statements

Hazard Statements: H250-H314

Catches fire spontaneously if exposed to air. Causes severe skin burns and eye damage.

Precautionary Statements: P210-P222-P260-P264b-P280-P301+P330+P331-P302+P334-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not allow contact with air. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN: Immerse in cool water/wrap in wet bandages. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.2
Packing Group
I
Harmonized Tariff Code
2931.39
TSCA
No

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