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41946 Magnesium nitride, 99.6% (metals basis)

CAS Number
12057-71-5
Synonyms

Stock No. Size Price ($) Quantity Availability
41946-09 10g 72.80
41946-18 50g 325.00
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Magnesium nitride, 99.6% (metals basis)

MDL
MFCD00016205
EINECS
235-022-1

Chemical Properties

Formula
Mg3N2
Formula Weight
100.95
Form
-325 Mesh Powder
Melting point
800° dec.
Density
2.71
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Reacts with water.

Applications

The use of magnesium nitride as a convenient source of ammonia allows a direct transformation of esters to primary amides. Methyl, ethyl, isopropyl, and tert-butyl esters are converted to the corresponding carboxamides in good yields.

Notes

Store under dry inert gas.

Literature References

Gemma E. Veitch.; Katy L. Bridgwood.; and Steven V. Ley. Magnesium Nitride as a Convenient Source of Ammonia: Preparation of Primary Amides.Org. Lett.2008,10(16), 3623-3625.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H315-H319-H335

Flammable solid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P240-P241-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.1
Packing Group
II
Harmonized Tariff Code
2850.00
TSCA
Yes

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