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42097 Bromopentacarbonylrhenium(I), 98%

CAS Number
14220-21-4
Synonyms
Pentacarbonylbromorhenium(I)
Rhenium(I) pentacarbonyl bromide

Stock No. Size Price ($) Quantity Availability
42097-03 1g 268.00
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Bromopentacarbonylrhenium(I), 98%

MDL
MFCD00013295
EINECS
238-084-8

Chemical Properties

Formula
C5BrO5Re
Formula Weight
406.16
Form
Crystalline
Melting point
ca 90° subl.
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Ambient temperatures.
Solubility
Insoluble in water.

Applications

This is used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes. The starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion.

Notes

Air an d moisture sensitive. Handle under dry protective gas. Store under room temperature.

Literature References

L. C. Porter.; A. H. Reid.; J. P. Fackler Jnr. Structure of bromopentacarbonylrhenium(I). Acta Cryst. 1992, 48 (5),908-909.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H332

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Rinse mouth. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2853.90
TSCA
No

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