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42277 Gadolinium(III) isopropoxide, 99.9% (metals basis), 5% w/v in toluene/isopropanol (3:2)

CAS Number
14532-05-9
Synonyms

Stock No. Size Price ($) Quantity Availability
42277-AC 25ml 135.00
42277-AE 100ml 428.00
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Gadolinium(III) isopropoxide, 99.9% (metals basis), 5% w/v in toluene/isopropanol (3:2)

MDL
MFCD00144381

Chemical Properties

Formula
C9H21GdO3
Formula Weight
334.51
Form
Liquid
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Hydrolyzes slowly in water.

Applications

It is employed in the catalyst action which is used in a ring opening of meso-aziridines with trimethylsilyl azide. In many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome.

Notes

Hygroscopic. Incompatible with strong oxidizing agents. Store in dry place.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H304-H314-H335-H336-H361d-H373

Highly flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2846.90
TSCA
No

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