Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

42277 Gadolinium(III) isopropoxide, 99.9% (metals basis), 5% w/v in toluene/isopropanol (3:2)

CAS Number

Stock No. Size Price ($) Quantity Availability
42277-AC 25ml 135.00
42277-AE 100ml 428.00
Add to Cart Bulk/Specialty Print Quote View Item

Gadolinium(III) isopropoxide, 99.9% (metals basis), 5% w/v in toluene/isopropanol (3:2)


Chemical Properties

Formula Weight
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Hydrolyzes slowly in water.


It is employed in the catalyst action which is used in a ring opening of meso-aziridines with trimethylsilyl azide. In many asymmetric catalysis applications, glove box and Schlenk techniques should be employed to prevent exposure of the rare earth catalyst to air and moisture, which can be detrimental to the reaction outcome.


Hygroscopic. Incompatible with strong oxidizing agents. Store in dry place.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H304-H314-H335-H336-H361d-H373

Highly flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of damaging the unborn child. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
Packing Group
Harmonized Tariff Code


  • B21202

    6-Fluoroveratraldehyde, 97+%
  • J67089

    Gold nanoparticles, 5nm, supplied in 0.1mM PBS, 95%, OD1, 515-520nm absorption
  • 42259

    Aluminum slug, 3.175mm (0.125in) dia x 6.35mm (0.25in) length, Puratronic®, 99.999% (metals basis)
  • B20620

    3,4,5-Trihydroxybenzamide, 98%
  • H27381

    6-Hydroxy-3-iodo-2-methylpyridine, 95%

Recently Viewed


Life Science

Metals & Materials


Analytical & Labware