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Hydrogenolysis of benzyl-nitrogen bondsPalladium hydroxide, Pd 20% on carbon, nominally 50% water is used as a catalyst for hydrogenolysis of benzyl groups and epoxides. It is used to reduce nitro compounds to amines. It acts as a dehydrogenation reagent as well as a useful reagent for debenzylation.
Bedford, R. B.; Bowen, J. G.; Davidson, R. B.; Haddow, M. F.; Seymour-Julen, A. E.; Sparkes, H. A.; Webster, R. L. Facile Hydrolysis and Alcoholysis of Palladium Acetate. Angew. Chem. Int. Ed. 2015, 54 (22), 6591-6594.
Zhang, Z.; Fukuzaki, T.; Myers, A. G. Synthesis of D-Desosamine and Analogs by Rapid Assembly of 3-Amino Sugars. Angew. Chem. Int. Ed. 2015, 55 (2), 523-527.
Demerzhan, S.; Gilbertson, S. R. Palladium-NHC catalyzed formation of cyclopenta[b]benzofurans and their subsequent modification. Tetrahedron Lett. 2015, 56 (23), 3633-3635.
Hazard Statements: H228
Precautionary Statements: P210-P240-P241-P280-P370+P378q
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use CO2, dry chemical, or foam