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42859 Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
100-58-3
Synonyms

Stock No. Size Price ($) Quantity Availability
42859-AE 100ml 48.50
42859-AP 500ml 170.00
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Phenylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00000038

Chemical Properties

Formula
C6H5MgBr
Formula Weight
181.31
Form
Liquid
Density
1.14
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Light Sensitive. May form a Precipitate. Store under Argon. Ambient temperatures.
Solubility
Miscible with tetrahydrofuran.

Applications

Phenylmagnesium bromide is an important reagent called as Grignard reagent used in the synthesis of organic and oraganometallic reactions. It is used to prepare phenyl aryl sulphides, sulphoxides, and sulphones. It acts as a strong acid and Lewis acid and undergoes addition reaction with many unsaturated functional groups. It is involved in the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s, 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol, o-substituted benzophenones and 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol. In addition to this, it is used for the monalkylation of primary amines to get secondary amines.

Notes

Air, moisture and light sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, strong oxidizing agents, strong acids and alcohols.

Literature References

Shimizu, D.; Oh, J.; Furukawa, K.; Kim, D.; Osuka, A. meso-Hydroxysubporphyrins: A Cyclic Trimeric Assembly and a Stable meso-Oxy Radical. Angew. Chem. 2015, 127 (22), 6713-6717.

Kiefer, G.; Riedel, T.; Dyson, P. J.; Scopelliti, R.; Severin, K. Synthesis of Triazenes with Nitrous Oxide. Angew. Chem. Int. Ed. 2015, 54 (1), 302-305.

GHS Hazard and Precautionary Statements

Hazard Statements: H224-H314-H335-H336

Extremely flammable liquid and vapour. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause drowsiness or dizziness.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
Yes

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