Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

42965 Borane-dimethyl sulfide complex, 2M in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
13292-87-0
Synonyms

Stock No. Size Price ($) Quantity Availability
42965-AE 100ml 59.90
42965-AP 500ml 231.00
Add to Cart Bulk/Specialty Print Quote View Item

Borane-dimethyl sulfide complex, 2M in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00013189

Chemical Properties

Formula
C2H9BS
Formula Weight
75.97
Form
Liquid
Flash Point
-17°(-1°F)
Density
0.855
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Miscible with ethyl ether, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents.

Applications

Borane- dimethyl sulfide is used for hydroboration and reduction reactions. It is used in the reduction of aldehydes, ketones, epoxides and carboxylic acids to give corresponding alcohols. It is also involved in the Corey-Itsuno reduction. It acts as an intermediate in the preparation of highly pure semiconductor. It is also employed as a rocket propellant.

Notes

Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Store in a cool place. Incompatible with acids, water, alcohols, bromine, acid anhydrides, acid chlorides and oxidizing agents.

Literature References

James, S. N.; Coster, M. J. Synthesis of N-alkylsulfonamides by borane-dimethyl sulfide reduction of N-acylsulfonamides. Tetrahedron Lett. 2015, 56 (16), 2059-2061.

Xie, Z.; Zhou, T.; Gou, Y. Synthesis and characterization of zirconium diboride ceramic precursor. Ceram. Int. 2015, 41 (5), 6226-6231.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H260-H302-H315-H318-H335-H336-H351

Highly flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer.

Precautionary Statements: P201-P202-P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P264b-P270-P271-P281-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P330-P332+P313-P335+P334-P363

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation occurs: Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse.

Other References

Beilstein
3663489
Hazard Class
4.3
Packing Group
I
Harmonized Tariff Code
2942.00
TSCA
Yes

Recommended

  • A10173

    Trifluoromethanesulfonic acid, 98+%
  • A10275

    2-Bromoethanol, 97%
  • A10348

    Benzaldehyde, 99+%
  • L13961

    Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4
  • 44608

    Tetrahydrofuran, anhydrous, 99.8+%, stab. with 0.025% BHT, packaged under Argon in resealable ChemSeal™ bottles

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware