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42967 Borane-dimethyl sulfide complex, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
13292-87-0
Synonyms

Stock No. Size Price ($) Quantity Availability
42967-AA 5ml 17.50
42967-AC 25ml 46.70
42967-AE 100ml 124.00
42967-AP 500ml 445.00
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Borane-dimethyl sulfide complex, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00013189
EINECS
236-313-6

Chemical Properties

Formula
C2H9BS
Formula Weight
75.97
Form
Liquid
Melting point
-38°
Boiling Point
ca 44° dec.
Flash Point
-1°(31°F)
Density
0.801
Refractive Index
1.4570
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Ambient temperatures.
Solubility
Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents.

Applications

Borane- dimethyl sulfide is used for hydroboration and reduction reactions. It is used in the reduction of aldehydes, ketones, epoxides and carboxylic acids to give corresponding alcohols. It is also involved in the Corey-Itsuno reduction. It acts as an intermediate in the preparation of highly pure semiconductor. It is also employed as a rocket propellant.

Notes

Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Store in a cool place. Incompatible with acids, water, alcohols, bromine, acid anhydrides, acid chlorides and oxidizing agents.

Literature References

Xie, Z.; Deng, X.; Suo, X.; Zhou, T.; Gou, Y. Synthesis and characterization of zirconium diboride precursor based on polycentric bridge bonds. Mater. Chem. Phys. 2015, 159, 178-184.

.

Kang, Y. G.; Park, C. Y.; Shin, H.; Singh, R.; Arora, G.; Yu, C. M.; Lee, I. Y. Synthesis and anti-tubercular activity of 2-nitroimidazooxazines with modification at the C-7 position as PA-824 analogs. Bioorg. Med. Chem. Lett. 2015, 25 (17), 3650-3653.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H260-H301-H315-H318-H335

Highly flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. Toxic if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P280-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P335+P334-P363-P370+P378

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse. In case of fire: Use for extinction:

Other References

Beilstein
3663489
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2942.00
TSCA
Yes
RTECS
PV5080000

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