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43085 Palladium(II) chloride, Premion®, 99.999% (metals basis), Pd 59.5% min

CAS Number
7647-10-1
Synonyms

Stock No. Size Price ($) Quantity Availability
43085-03 1g 91.80
43085-06 5g 368.00
43085-14 25g 1558.00
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Palladium(II) chloride, Premion®, 99.999% (metals basis), Pd 59.5% min

MDL
MFCD00003558
EINECS
231-596-2

Chemical Properties

Formula
PdCl2
Formula Weight
177.31
Form
Powder
Melting point
675° dec.
Density
4.0
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in cold water, organic solvents and hydrochloric acid.

Applications

Palladium(II) chloride is used to remove the stain present stainless steel . Its solutions are used to test the corrosion-resistance of stainless steel. It is used in carbon monoxide detectors. It is also used for cosmetic tatooing of leukomas in thecornea and in the preparation of palladium(II) iodide by reacting with potassium iodide. It is involved in the synthesis of semiconducting metal-containing polymers. It is used as a catalyst for carbonylation of organic tellurides and deamination of phenethylamines to phenyl substituted pyrroles with copper(I) as co catalyst. It plays an important role in the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.

Notes

Moisture sensitive. Incompatible with organic solvents, acids, ammonia, zinc, strong oxidizing agents, aluminum, magnesium, nitrates and thiocyanates.

Literature References

Yamaguchi, T.; Yamaguchi, E.; Tada, N.; Itoh, A. Direct ortho-Hydroxylation of 2-Phenylpyridines using Palladium(II) Chloride and Hydrogen Peroxide. Adv. Synth. Catal. 2015, 357 (9), 2017-2021.

Banti, C. N.; Charalampou, D. C.; Kourkoumelis, N.; Owczarzak, A. M.; Kubicki, M.; Hadjikakou, S. K.; Hadjiliadis, N. Mono-nuclear cis-Pd(II) chloride complex of the thio-nucleotide analogue 5-methyl-thiouracil and its biological activity. Polyhedron 2015, 87, 251-258.

GHS Hazard and Precautionary Statements

Hazard Statements: H290-H302-H317-H318

May be corrosive to metals. Harmful if swallowed. May cause an allergic skin reaction. Causes serious eye damage.

Precautionary Statements: P234-P264b-P270-P272-P280-P301+P312-P302+P352-P305+P351+P338-P310-P330-P333+P313-P363-P390-P501c

Keep only in original container. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,6990
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
RT3500000

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