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43291 Borane-tetrahydrofuran complex, 1M soln. in THF, packaged under Argon in resealable ChemSeal™ bottles

CAS Number
14044-65-6
Synonyms
BTHF

Stock No. Size Price ($) Quantity Availability
43291-AE 100ml 45.60
43291-AP 500ml 183.00
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Borane-tetrahydrofuran complex, 1M soln. in THF, packaged under Argon in resealable ChemSeal™ bottles

MDL
MFCD00012429
EINECS
237-881-8

Chemical Properties

Formula
C4H11BO
Formula Weight
85.94
Form
Liquid
Flash Point
-21°(-8°F)
Density
0.878
Storage & Sensitivity
Keep Cold. Moisture Sensitive. Air Sensitive. Store under Argon.
Solubility
Miscible and reacts violently with water.

Applications

Borane-tetrahydrofuran complex is an important reagent used in the reduction of certain functional groups viz. aldehyde, ketone, carboxylic acid, amide, oxime, imine and nitrile. It is also used as hydro borating agent. It acts as a borane source for oxazaborolidine catalyzed asymmetric reductions. It is utilized to reduce nylon surface amide groups to secondary amines.

Notes

Air and moisture sensitive. Forms explosive peroxides in contact with air. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents and alcohols. On hydrolysis, it forms hydrogen and boric acid.

Literature References

Wang, X.; Xie, L.; Huang, K. W.; Lai, Z. A rationally designed amino-borane complex in a metal organic framework: a novel reusable hydrogen storage and size-selective reduction material. Chem. Commun. 2015, 51 (36), 7610-7613.

Zhou, Y.; Yen, C. H.; Fu, S.; Yang, G.; Zhu, C.; Du, D.; Wo, P. C.; Cheng, X.; Yang, J.; Wai, C. M.; Lin, Y. One-pot synthesis of B-doped three-dimensional reduced graphene oxide via supercritical fluid for oxygen reduction reaction. Green Chem. 2015, 17 (6), 3552-3560.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H260-H302-H315-H318-H335-H336-H351

Highly flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer.

Precautionary Statements: P201-P202-P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P261-P264b-P270-P271-P281-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P308+P313-P310-P330-P332+P313-P335+P334

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation occurs: Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.

Other References

Beilstein
3668402
Hazard Class
4.3
Packing Group
I
Harmonized Tariff Code
2932.19
TSCA
Yes

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