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43364 Ruthenium(III) chloride hydrate, Premion®, 99.99% (metals basis)

CAS Number
14898-67-0
Synonyms

Stock No. Size Price ($) Quantity Availability
43364-04 2g 133.00
43364-09 10g 596.00
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Ruthenium(III) chloride hydrate, Premion®, 99.99% (metals basis)

MDL
MFCD00149844
EINECS
233-167-5

Chemical Properties

Formula
RuCl3•xH2O
Formula Weight
207.43(anhy)
Form
Crystalline
Melting point
100°dec
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Soluble in water.

Applications

Ruthenium(III) chloride hydrate is used as a starting material in ruthenium chemistry. It acts as a precursor to many ruthenium compounds, which finds application as catalysts in asymmetric hydrogenation and alkene metathesis. It serves as a catalyst in the preparation of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine. Further, it is used in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst for the efficient dehydrogenation of arylmethyl alcohols to the corresponding aldehydes.

Notes

Hygroscopic. Incompatible with oxidizing agents, bases, zinc and metals.

Literature References

Wang, J.; Zhao, J.; Osterloh, F. E. Photochemical charge transfer observed in nanoscale hydrogen evolving photocatalysts using surface photovoltage spectroscopy. Energy Environ. Sci. 2015, 8 (10), 2970-2976.

Nazarov, A. A.; Meier, S. M.; Zava, O.; Nosova, Y. N.; Milaeva, E. R.; Hartinger, C. G.; Dyson, P. J. Protein ruthenation and DNA alkylation: chlorambucil-functionalized RAPTA complexes and their anticancer activity. Dalton Trans. 2015, 44 (8), 3614-3623.

GHS Hazard and Precautionary Statements

Hazard Statements: H290-H302-H314-H335

May be corrosive to metals. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P234-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P390-P501c

Keep only in original container. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,8302
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
VM2650000

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