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43370 5-Hexyn-1-ol, 97%

CAS Number
928-90-5
Synonyms

Stock No. Size Price ($) Quantity Availability
43370-03 1g 25.90
43370-06 5g 71.20
43370-14 25g 252.00
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5-Hexyn-1-ol, 97%

MDL
MFCD00002980

Chemical Properties

Formula
C6H10O
Formula Weight
98.15
Form
Liquid
Boiling Point
73-75°/15mm
Flash Point
70°(158°F)
Density
0.880
Refractive Index
1.4451
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly miscible with water.

Applications

5-Hexyn-1-ol is used as starting material for the preparation of terminal alkynes and lactones containing terminal alykyne groups. It is also used in the synthesis of cinnoline-fused cyclic enediyne, llycopodium alkaloids, (+)-nankakurine A and (+)-nankakurine B and 7-benzoyloxy-3-(2-nitrophenylseleno)-1,5-cyclodecadiyne.

Notes

Air and moisture sensitive. Keep the container tightly closed. Incompatible with strong oxidizing agents, acid anhydrides and acid chlorides.

Literature References

Bellina, F.; Lessi, M.; Marianetti, G.; Panattoni, A. Highly regioselective C-5 alkynylation of imidazoles by one-pot sequential bromination and Sonogashira cross coupling. Tetrahedron Lett. 2015, 56 (25), 3855-3857.

Park, H. J.; Kim, J. E.; Yum, E. K.; Kim, Y. H.; Han, C. W. Copper- and Ligand-free Heteroannulation of o-Halohydroxypyridine with Terminal Alkynes Using Pd/C Catalyst: One-Pot Synthesis of 2-Substituted Furopyridines and their Functionalization. Bull. Korean Chem. Soc. 2015, 36 (1), 211-218.

GHS Hazard and Precautionary Statements

Hazard Statements: H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P235-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep cool. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2905.29
TSCA
No

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