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43393 Neodymium(III) trifluoromethanesulfonate, 98%

CAS Number
34622-08-7
Synonyms

Stock No. Size Price ($) Quantity Availability
43393-09 10g 69.60
43393-18 50g 300.00
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Neodymium(III) trifluoromethanesulfonate, 98%

MDL
MFCD00192343

Chemical Properties

Formula
Nd(OSO2CF3)3
Formula Weight
591.44
Form
Powder
Density
1.7
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water.

Applications

Neodymium(III) trifluoromethanesulfonate is used in the Aldol reaction of silyl enol ethers with aldehydes and as a catalyst for dehydration of fructose, Diels-Alder reactions of cyclopentadiene and alkyl acrylates, α-amination reactions of pyrazolones, polymerization reactions of cyclosiloxanes, direct polycondensation of dicarboxylic acids and diols, regioselective reductive ring opening of benzylidene acetals, Paal-Knorr cyclocondensation and nitration of benzene.

Notes

Store in dry, dark and ventilated place. Keep container tightly sealed. Incompatible with oxidizing agents.

Literature References

Andrej Pevec.; Maja Mrak.; Alojz Demšar.; Saša Petricek.; Herbert W Roesky. Coordination number 12 in praseodymium and 11 in neodymium complexes with organofluorotitanate ligands. Polyhedron. 2003, 22, (4), 575-579.

D'Angelo, P.; De Panfilis, S.; Filipponi, A.; Persson, I. High-Energy X-ray Absorption Spectroscopy: A New Tool for Structural Investigations of Lanthanoids and Third-Row Transition Elements. Chemistry-A European Journal. 2008, 14 (10), 3045-3055.

GHS Hazard and Precautionary Statements

Hazard Statements: H314

Causes severe skin burns and eye damage.

Precautionary Statements: P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2846.90
TSCA
No

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