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43409 Rhodium, 1% on Polyethyleneimine/SiO2 powder

CAS Number
7440-16-6
Synonyms

Stock No. Size Price ($) Quantity Availability
43409-06 5g 71.00
43409-14 25g 283.00
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Rhodium, 1% on Polyethyleneimine/SiO2 powder

MDL
MFCD00011201
EINECS
231-125-0

Chemical Properties

Form
Powder, 40-200 mesh
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Rhodium is a useful reagent for the conversation of nitriles to primary amines and the hydrogenation of aromatic rings, pyridines, aldehydes and sugars. It is also used for the reduction of oximes to amines and for the reduction of nitrobenzene to phenylhydroxylamine using hydrazine hydrate as the hydrogen source.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, halogens, chlorine trifluoride and oxygen difluoride.

Literature References

Paulo A.Z. Suarez.; Jeane E.L. Dullius.; Sandra Einloft.; Roberto F. De Souza.; Jairton Dupont. The use of new ionic liquids in two-phase catalytic hydrogenation reaction by rhodium complexes. Polyhedron. 1996, 15 (7), 1217-1219.

Henri B. Kagan. Asymmetric catalytic reduction with transition metal complexes. I. Catalytic system of rhodium(I) with (-)-2,3-0-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane, a new chiral diphosphine. J. Am. Chem. Soc. 1972, 94 (18), 6429-6433.

GHS Hazard and Precautionary Statements

Hazard Statements: H373

May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P314-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Get medical advice/attention if you feel unwell. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
3815.12
TSCA
Yes

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