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Rhodium is a useful reagent for the conversation of nitriles to primary amines and the hydrogenation of aromatic rings, pyridines, aldehydes and sugars. It is also used for the reduction of oximes to amines and for the reduction of nitrobenzene to phenylhydroxylamine using hydrazine hydrate as the hydrogen source.
Paulo A.Z. Suarez.; Jeane E.L. Dullius.; Sandra Einloft.; Roberto F. De Souza.; Jairton Dupont. The use of new ionic liquids in two-phase catalytic hydrogenation reaction by rhodium complexes. Polyhedron. 1996, 15 (7), 1217-1219.
Henri B. Kagan. Asymmetric catalytic reduction with transition metal complexes. I. Catalytic system of rhodium(I) with (-)-2,3-0-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane, a new chiral diphosphine. J. Am. Chem. Soc. 1972, 94 (18), 6429-6433.
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