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43430 Tin(II) bromide, 99.2%

CAS Number
10031-24-0
Synonyms

Stock No. Size Price ($) Quantity Availability
43430-06 5g 19.80
43430-14 25g 66.40
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Tin(II) bromide, 99.2%

MDL
MFCD00011239
EINECS
233-087-0

Chemical Properties

Formula
SnBr2
Formula Weight
278.51
Form
Powder
Melting point
215°
Boiling Point
623°
Density
5.12
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in alcohol, ether, acetone, pyridine and dimethyl sulfoxide.

Applications

Stannous bromide acts a lewis acid. It is used to prepare alkyl tin compounds and in the spectrophotometric determination of iridium. It is involved in regioselective mono-etherfications of vicinal diols with diazo compounds. It acts as a catalyst to produce resinous lactone high polymers. It serves as a potent reducing agent.

Notes

Moisture, air and light sensitive. Store in a tightly closed container. Prolonged exposure to atmosphere may degrade the product.

Literature References

Braunschweig, H.; Ceik, M. A.; Dewhurst, R. D.; Heid, M.; Hupp, F.; Sen, S. S. Stepwise isolation of low-valent, low-coordinate Sn and Pb mono- and dications in the coordination sphere of platinum. Chem. Sci. 2015, 6, 425-435.

Avery, J. C.; Hanson, M. A.; Herber, R. H.; Bladek, K. J.; Rupar,P. A.; Nowik, I.; Huang, Y.; Baines, K. M. Cationic Cryptand Complexes of Tin(II). Inorg. Chem. 2012, 51 (13), 7306-7316.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H314-H335

Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,8782
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2827.59
TSCA
Yes

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