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Palladium(II) bromide is used as a source of the palladium(0) precatalyst in various coupling reactions. It is used as a catalyst for the carbonylative Heck coupling reaction. It is also used as an oxidizing agent in organic synthesis.
Li, Y.; Dai, Y.; Tian, X. K. One-Pot Synthesis of Monodisperse Palladium Tin Nanoparticles with Controlled Composition and Size and Its Catalytic Ability Study. Catal. Lett. 2015, 145 (10), 1837-1844.
Tanaka, D.; Romeril, S. P.; Myers, A. G. On the mechanism of the palladium(II)-catalyzed decarboxylative olefination of arene carboxylic acids. Crystallographic characterization of non-phosphine palladium(II) intermediates and observation of their stepwise transformation in Heck-like processes. J. Am. Chem. Soc. 2005, 127 (29), 10323-10333.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant