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43697 Palladium(II) bromide, Premion®, 99.998% (metals basis), Pd 39.5% min

CAS Number
13444-94-5
Synonyms

Stock No. Size Price ($) Quantity Availability
43697-03 1g 85.80
43697-06 5g 385.00
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Palladium(II) bromide, Premion®, 99.998% (metals basis), Pd 39.5% min

MDL
MFCD00011170
EINECS
236-588-2

Chemical Properties

Formula
PdBr2
Formula Weight
266.22
Form
Powder
Melting point
dec.
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water. Soluble in hydrogen bromide.

Applications

Palladium(II) bromide is used as a source of the palladium(0) precatalyst in various coupling reactions. It is used as a catalyst for the carbonylative Heck coupling reaction. It is also used as an oxidizing agent in organic synthesis.

Notes

Incompatible with strong oxidizing agents.

Literature References

Li, Y.; Dai, Y.; Tian, X. K. One-Pot Synthesis of Monodisperse Palladium Tin Nanoparticles with Controlled Composition and Size and Its Catalytic Ability Study. Catal. Lett. 2015, 145 (10), 1837-1844.

Tanaka, D.; Romeril, S. P.; Myers, A. G. On the mechanism of the palladium(II)-catalyzed decarboxylative olefination of arene carboxylic acids. Crystallographic characterization of non-phosphine palladium(II) intermediates and observation of their stepwise transformation in Heck-like processes. J. Am. Chem. Soc. 2005, 127 (29), 10323-10333.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
Yes

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