Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

44030 Hydridotetrakis(triphenylphosphine)rhodium(I), Rh 8.9% min

CAS Number
18284-36-1
Synonyms

Stock No. Size Price ($) Quantity Availability
44030-03 1g 260.00
44030-06 5g 978.00
Add to Cart Bulk/Specialty Print Quote View Item

Hydridotetrakis(triphenylphosphine)rhodium(I), Rh 8.9% min

MDL
MFCD00015867

Chemical Properties

Formula
RhH[P(C6H5)3]4
Formula Weight
1153.09
Form
Powder
Melting point
145-147° dec.
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Soluble in chloroform, toluene

Applications

It finds its application as a catalyst for hydrogenation of alkenes and hydrosilylation of alkynes.

Notes

Air sensitive. Protect from air and oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Literature References

T.H. Chan, et al. HydridoFull-size image (<1 K)(triphenylphosphine)rhodium(I) as an effective catalyst for the regiospecific hydrosilation of α,β-unsaturated carbonyl compounds.Tetrahedron Lett.,21993,34(19), 3095-3098.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware