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44036 Bis(norbornadiene)rhodium(I) tetrafluoroborate

CAS Number
36620-11-8
Synonyms

Stock No. Size Price ($) Quantity Availability
44036-03 1g 274.00
44036-06 5g 1025.00
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Bis(norbornadiene)rhodium(I) tetrafluoroborate

MDL
MFCD00671775

Chemical Properties

Formula
[Rh(C7H8)2]BF4
Formula Weight
373.99
Form
Powder
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Fairly soluble in dichloromethane. Insoluble in water.

Applications

Bis(norbornadiene)rhodium(I) tetrafluoroborate is used in hydrogenation, Isomerization reactions.

Notes

Air and moisture sensitive. Store in cool, dry place in tightly closed container. Store away from oxidizing agents.

Literature References

G. Svensson,; J. Albertsson,; T. Frejd,; T. Klingstedt.[(+)-(R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethylbiphenyl](8,9,10-trinorborna-2,5-diene)rhodium(I) tetrafluoroborate . Acta Cryst. 1986, 42(10),1324-1327 .

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2843.90
TSCA
No

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