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44129 Lithium methoxide, 98+%

CAS Number
865-34-9
Synonyms

Stock No. Size Price ($) Quantity Availability
44129-14 25g 53.80
44129-22 100g 157.00
44129-36 500g 587.00
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Lithium methoxide, 98+%

MDL
MFCD00036357
EINECS
212-737-7

Chemical Properties

Formula
CH3LiO
Formula Weight
37.98
Form
Powder
Melting point
>500° dec.
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Ambient temperatures.
Solubility
Soluble in methanol.

Applications

Lithium methoxide is used in sol-gel synthesis of lithium borophosphates. It is also useful for deprotonation reactions in organic synthesis. Further, it serves as a mild base in organic synthesis especially in transesterifications.

Notes

Air and moisture sensitive. Incompatible with chlorinated solvents, acids and water.

Literature References

Tarakanov, P. A.; Simakov, A. O.; Tolbin, A. Y.; Balashova, I. O.; Shestov, V. I.; Tomilova, L. G. Novel A3B-type tert-butyl-substituted tribenzodiazepinoporphyrazine: Synthesis, spectral properties and DFT study. Spectrochim. Acta, Part A 2015, 139, 464-470.

Wang, E.; Shen, J.; Wang, Y.; Tang, S.; Emami, S.; Reaney, M. J. T. Production of biodiesel with lithium glyceroxide. Fuel 2015, 160, 621-628.

GHS Hazard and Precautionary Statements

Hazard Statements: H251-H314

Self-heating: may catch fire. Causes severe skin burns and eye damage.

Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
3552389
Hazard Class
4.2
Packing Group
II
Harmonized Tariff Code
2905.19
TSCA
Yes

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