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44129 Lithium methoxide, 98+%

CAS Number
865-34-9
Synonyms

Stock No. Size Price ($) Quantity Availability
44129-14 25g 55.40
44129-22 100g 162.00
44129-36 500g 616.00
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Lithium methoxide, 98+%

MDL
MFCD00036357
EINECS
212-737-7

Chemical Properties

Formula
CH3LiO
Formula Weight
37.98
Form
Powder
Melting point
>500° dec.
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Ambient temperatures.
Solubility
Soluble in methanol.

Applications

Lithium methoxide is used in sol-gel synthesis of lithium borophosphates. It is also useful for deprotonation reactions in organic synthesis. Further, it serves as a mild base in organic synthesis especially in transesterifications.

Notes

Air and moisture sensitive. Incompatible with chlorinated solvents, acids and water.

Literature References

Tarakanov, P. A.; Simakov, A. O.; Tolbin, A. Y.; Balashova, I. O.; Shestov, V. I.; Tomilova, L. G. Novel A3B-type tert-butyl-substituted tribenzodiazepinoporphyrazine: Synthesis, spectral properties and DFT study. Spectrochim. Acta, Part A 2015, 139, 464-470.

Wang, E.; Shen, J.; Wang, Y.; Tang, S.; Emami, S.; Reaney, M. J. T. Production of biodiesel with lithium glyceroxide. Fuel 2015, 160, 621-628.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-X

Causes severe skin burns and eye damage.

Precautionary Statements: P235+P410-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Keep cool. Protect from sunlight. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3552389
Hazard Class
4.2
Packing Group
II
Harmonized Tariff Code
2905.19
TSCA
Yes

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