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Catalyst for isomerization and hydrosilyltion of unsaturated compounds. Co-catalyst for oligomerization/cyclooligomerization or polymerization of alkenes, Bis(1,5-cyclooctadiene)nickel(0) is used as a catalyst for the cycloaddition of 1,3-dienes and used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. It is involved as a catalyst for asymmetric alpha-arylation and heteroarylation of ketones with chloroarenes, stereoselective borylative ketone-diene coupling, cycloaddition of benzamides with internal alkynes and methyl carboxylation of homopropargylic alcohols.
Zhou, Q.; Srinivas, H. D.; Dasgupta, S; Watson, M. P. Nickel-Catalyzed Cross-Couplings of Benzylic Pivalates with Arylboroxines: Stereospecific Formation of Diarylalkanes and Triarylmethanes. J. Am. Chem. Soc. 2013, 135 (9), 3307-3310.
Magano, J.; Monfette, S. Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling. ACS Catal. 2015, 5 (5), 3120-3123.
Standley, E. A.; Smith, S. J.; Müller, P.; Jamison, T. F. A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes. Organometallics. 2014, 33 (8), 2012-2018.
Hazard Statements: H228-H317-H350
Flammable solid. May cause an allergic skin reaction. May cause cancer.
Precautionary Statements: P201-P202-P210-P240-P241-P261-P270-P272-P280-P302+P352-P308+P313-P333+P313-P363-P370+P378q-P501c
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant