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44226 Lithium perchlorate, anhydrous, 99.99% (metals basis)

CAS Number
7791-03-9
Synonyms

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Bulk/Specialty

Lithium perchlorate, anhydrous, 99.99% (metals basis)

MDL
MFCD00011079
EINECS
232-237-2

Chemical Properties

Formula
LiClO4
Formula Weight
106.40
Form
Lumps, Ampouled under argon
Melting point
236°
Boiling Point
400° dec.
Density
2.43
Storage & Sensitivity
Hygroscopic. Store under Argon. Ambient temperatures.
Solubility
Partially soluble in water (30% at 25°, 72% at 100°). Soluble in alcohol, acetone, ether, ethyl acetate.

Applications

Used as intermediates. An effective protein denaturant. It may be useful as a component in the development of biopolymers and biofilms. Acts as a catalyst in the solvent free thiolysis of epoxides. Used in various organic transformations.

Notes

Hygroscopic. Store under inert gas. Store away from incompatibles.

Literature References

Mark A. Forman.; William P. Dailey. The lithium perchlorate-diethyl ether rate acceleration of the Diels-Alder reaction: Lewis acid catalysis by lithium ion.J. Am. Chem. Soc.1991,113(7), 2761-2762.

GHS Hazard and Precautionary Statements

Hazard Statements: H271-H315-H319-H335

May cause fire or explosion; strong oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P220-P221-P261-P264b-P271-P280-P283-P302+P352-P304+P340-P305+P351+P338-P306+P360-P312-P332+P313-P337+P313-P363-P370+P378q-P371+P380+P375-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear fire/flame resistant/retardant clothing. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,5539
Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2829.90
TSCA
Yes

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