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Applied as a starting material for homometallic, trinuclear heteroscorpionate complexes applied in studies of electronic and magnetic properties.
Donald F Cook.; Neil F Curtis.; Olga P Gladkikh.; David C Weatherburn. Compounds of nickel(II) with 5RS,7RS,12RS,14RS-5,12-dimethyl-7,14-diphenyl-1,4,8,11-tetraazacyclotetradecane, rrL2; the structures of [Ni(rrL2)(acac)]ClO4 and [Ni(rrL2)][ZnCl4]·MeNO2. Inorg. Chim. Acta.2003,355(20),15-24.
Hazard Statements: H272-H314-H317-H334-H335-H341-H350-H360-H372
May intensify fire; oxidizer. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing genetic defects. May cause cancer. May damage fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure.
Precautionary Statements: P201-P202-P210-P220-P221-P260-P264b-P270-P271-P272-P280g-P281-P285-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P333+P313-P363-P370+P378q-P501c
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant