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44376 Tris[N,N-bis(trimethylsilyl)amide]europium(III), 98%

CAS Number
35789-02-7
Synonyms
Europium(III) tris[N,N-bis(trimethylsilyl)amide]

Stock No. Size Price ($) Quantity Availability
44376-01 0.25g 38.20
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Tris[N,N-bis(trimethylsilyl)amide]europium(III), 98%

MDL
MFCD03411248

Chemical Properties

Formula
C18H54EuN3Si6
Formula Weight
633.13
Form
Powder
Melting point
180-184°
Boiling Point
105°10|-^4mm
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Soluble in water, protic solvents.

Applications

Tris[N,N-bis(trimethylsilyl)amide]europium(III) is used as a reactant for Preferential complexation reactions, Pin-wheel shaped heterobimetallis lanthanide alkali metal binaphtholates, It is also used as a reactant for the synthesis of Isostructural neo-pentoxide derivatives of Group 3 and lanthanide series metals for production of Ln2O3 nanoparticles, Anhydrous mononuclear tris(8-quinolinolato)lanthanoid complexes for organic light-emitting devices

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Never allow product to get in contact with water during storage. Air, moisture sensitive. Hydrolyses readily. Handle and store under inert gas. Keep away from Strong oxidizing agents.

Literature References

FT Edelmann. Lanthanide amidinates and guanidinates: from laboratory curiosities to efficient homogeneous catalysts and precursors for rare-earth oxide thin films. Chemical Society Reviews. 2009 38, (1) , 2253-2268.

GB Deacon.; CM Forsyth.; PC Junk.; J Wang. Reduction of Carbodiimides by Samarium (II) Bis (trimethylsilyl) amides Formation of Oxalamidinates and Amidinates through CC Coupling or CH Activation. Inorganic chemistry. 2007 46, (23) , 10022-10030.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H261-H314-H335

Flammable solid. In contact with water releases flammable gas. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P223-P231+P232-P240-P241-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P335+P334-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
II
Harmonized Tariff Code
2846.90
TSCA
No

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