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312959-24-3 - 1,2,3,4,5-Pentaphenyl-1'-(di-tert-butylphosphino)ferrocene, CTC-Q-PHOS, 95% - 44618 - Alfa Aesar

44618 1,2,3,4,5-Pentaphenyl-1'-(di-tert-butylphosphino)ferrocene, CTC-Q-PHOS, 95%

CAS Number
312959-24-3
Synonyms

Size Price ($) Quantity Availability
0.1g 72.70
0.5g 256.00
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1,2,3,4,5-Pentaphenyl-1'-(di-tert-butylphosphino)ferrocene, CTC-Q-PHOS, 95%

MDL
MFCD03788940

Chemical Properties

Formula
C48H47FeP
Formula Weight
710.72
Form
Powder, packaged under argon
Solubility
Soluble in ether, benzene, toluene and terahydrofuran.

Applications

Heck and Suzuki reactions1,2,3,4,5-Pentaphenyl-1'-(di-tert-butylphosphino)ferrocene is a sterically hindered phosphine ligand, which is used in palladium-catalyzed amination, arylation and etherification reactions of aryl chlorides.

Notes

Incompatible with strong oxidizing agents.

Literature References

Pace, V.; Luisi, R. Expanding the Synthetic Portfolio of Organolithiums: Direct Use in Catalytic Cross-Coupling Reactions. ChemCatChem 2014, 6 (6), 1516-1519.

Colacot, T. J. The 2010 Nobel Prize in Chemistry: Palladium-Catalysed Cross-Coupling. Platinum Met. Rev. 2011, 55 (2), 84-90.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2931.39
TSCA
No

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    Dichlorobis[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II), Pd 15%

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