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44844 Dichlorobis(tricyclohexylphosphine)palladium(II)

CAS Number
29934-17-6
Synonyms

Stock No. Size Price ($) Quantity Availability
44844-03 1g 154.00
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Dichlorobis(tricyclohexylphosphine)palladium(II)

MDL
MFCD00191830

Chemical Properties

Formula
C36H66Cl2P2Pd
Formula Weight
738.18
Form
Powder
Storage & Sensitivity
Ambient temperatures.
Solubility
Moderately soluble in dichloromethane and chloroform. Sparingly soluble in benzene and toluene. Insoluble in water, alcohols, acetone, diethyl ether, and hexanes.

Applications

It is used as catalyst for C-C and C-N coupling reaction. It is used in the homogeneous carbonylation of chloroarenes under mild conditions.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Ensure good ventilation at the work place.

Literature References

Vladimir V. Grushin.; Corinne Bensimon.; Howard Alper. ichlorobis(tricyclohexylphosphine)palladium(II): Synthesis and Crystal Structure. An Exceptionally Simple and Efficient Preparation of Bis(tricyclohexylphosphine)palladium(0) Inorg. Chem. 1994, 33 (21),4804-4806.

William J. Marshall.; Vladimir V. Grushin. Palladium(II) and Palladium(0) Complexes of BINAP(O) (2-(Diphenylphosphino)-2‘-(diphenylphosphinyl)-1,1‘-binaphthyl) Organometallics. 2003, 22 (3),555-562.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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