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44844 Dichlorobis(tricyclohexylphosphine)palladium(II)

CAS Number
29934-17-6
Synonyms

Stock No. Size Price ($) Quantity Availability
44844-03 1g 158.00
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Dichlorobis(tricyclohexylphosphine)palladium(II)

MDL
MFCD00191830

Chemical Properties

Formula
C36H66Cl2P2Pd
Formula Weight
738.18
Form
Powder
Storage & Sensitivity
Ambient temperatures.
Solubility
Moderately soluble in dichloromethane and chloroform. Sparingly soluble in benzene and toluene. Insoluble in water, alcohols, acetone, diethyl ether, and hexanes.

Applications

It is used as catalyst for C-C and C-N coupling reaction. It is used in the homogeneous carbonylation of chloroarenes under mild conditions.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Ensure good ventilation at the work place.

Literature References

Vladimir V. Grushin.; Corinne Bensimon.; Howard Alper. ichlorobis(tricyclohexylphosphine)palladium(II): Synthesis and Crystal Structure. An Exceptionally Simple and Efficient Preparation of Bis(tricyclohexylphosphine)palladium(0) Inorg. Chem. 1994, 33 (21),4804-4806.

William J. Marshall.; Vladimir V. Grushin. Palladium(II) and Palladium(0) Complexes of BINAP(O) (2-(Diphenylphosphino)-2‘-(diphenylphosphinyl)-1,1‘-binaphthyl) Organometallics. 2003, 22 (3),555-562.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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