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44955 Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

CAS Number
16971-33-8
Synonyms

Stock No. Size Price ($) Quantity Availability
44955-03 1g 78.70
44955-06 5g 339.00
44955-14 25g 1525.00
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Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

MDL
MFCD00049804
EINECS
241-051-0

Chemical Properties

Formula
C55H46ClOP3Ru
Formula Weight
952.41
Form
Crystalline
Melting point
204-206° dec.
Storage & Sensitivity
Light Sensitive. Very Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubility
Insoluble in water, ethanol, and DMSO. Sparingly soluble in benzene, chloroform and acetone.

Applications

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).

Notes

Store in cool place. Air, moisture, and light sensitive. Incompatible with strong oxidizing agents.

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H312+H332-H315-H319-H335

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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