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44966 Chlorobis(cyclooctene)iridium(I) dimer, Ir nominally 42.9%

CAS Number
12246-51-4
Synonyms
Di-µ-chlorobis(cyclooctene)iridium(I)

Stock No. Size Price ($) Quantity Availability
44966-03 1g 182.00
44966-06 5g 735.00
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Chlorobis(cyclooctene)iridium(I) dimer, Ir nominally 42.9%

MDL
MFCD00213465

Chemical Properties

Formula
C32H56Cl2Ir2
Formula Weight
896.00
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in organic solvents.

Applications

Chlorobis(cyclooctene)iridium(I) dime is used as catalyst for Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand, Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions, Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions, Alkylation reactions, Guerbet reaction, Allylic amination reactions in a DNA-diene-iridium(I) hybrid system, Asymmetric hydroamination reactions.

Notes

keep container tightly closed. Store in cool, dry conditions in well sealed containers.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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