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44969 Tris(dibenzylideneacetone)dipalladium(0), complex with chloroform, Pd 20.6%

CAS Number
52522-40-4
Synonyms

Stock No. Size Price ($) Quantity Availability
44969-03 1g 89.80
44969-06 5g 352.00
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Tris(dibenzylideneacetone)dipalladium(0), complex with chloroform, Pd 20.6%

MDL
MFCD00075479

Chemical Properties

Formula
C51H42O3Pd2.CHCl3 O.C2H2GaKCH3CO
Formula Weight
1035.11
Form
Powder
Melting point
131-135°
Storage & Sensitivity
Keep Cold. Moisture Sensitive. Air Sensitive. Store under Nitrogen.
Solubility
Soluble in organic solvents. Insoluble in water.

Applications

Tris(dibenzylideneacetone)dipalladium(0) is used in Synthesis of nanosized palladium phosphides upon interaction with white phosphorous, Preparation of palladium triphenylphosphine carbonyl cluster complexes, Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions.

Notes

Air & Moisture Sensitive. Store in cool, dry conditions in well sealed containers.

Literature References

Cortlandt G. Pierpont.; Margaret C. Mazza. Crystal and molecular structure of tris(dibenzylideneacetone)dipalladium(0). Inorg. Chem. 1974, 13, (8), 1891-1895.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H320-H351

Harmful if swallowed. Causes skin irritation. Causes eye irritation. Suspected of causing cancer.

Precautionary Statements: P201-P202-P264b-P270-P280i-P281-P301+P312-P302+P352-P305+P351+P338-P308+P313-P330-P332+P313-P337+P313-P362-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear eye/face protection. Use personal protective equipment as required. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. If skin irritation occurs: If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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