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45512 Palladium(II) nitrate, solution, Pd 4-5% w/w (cont. Pd)

CAS Number
10102-05-3
Synonyms

Stock No. Size Price ($) Quantity Availability
45512-NB (c)5g 322.00
45512-ND (c)25g 1378.00
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Palladium(II) nitrate, solution, Pd 4-5% w/w (cont. Pd)

MDL
MFCD00011169
EINECS
233-265-8

Chemical Properties

Formula
N2O6Pd
Formula Weight
230.43
Form
Liquid
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with water and dilute nitric acid.

Applications

Palladium(II) nitrate dehydrate is used as a reactant for doping activated carbon for catalysis. It acts as a catalyst for hydrogenation of 1-heptyne and naphthalene. It serves as an important raw material for the preparation of platinum-palladium carbon alloy nanocatalysts for methanol-tolerant oxygen reduction reaction in fuel cells and in the synthesis of copper palladium alloy thin films. Furthermore, it is used in the synthesis of di-phenyl sulfide-modified palladium-titanium dioxide catalysts for acetylene hydrogenation.

Notes

Incompatible with bases, alkali metals, acetic anhydride, iron, copper, amines, reducing agents, alcohols, brass, aluminum, corrodes steel, acetonitrile and acrylonitrile.

Literature References

Poirot, R.; Bourgeois, D.; Meyer, D. Palladium Extraction by A Malonamide Derivative (DMDOHEMA) from Nitrate Media: Extraction Behavior and Third Phase Characterization. Solvent Extr. Ion Exch. 2014, 32 (5), 529-542.

Kim, S.; Lee, E.; Park, K. M.; Lee, S. S. Exocyclic coordination chemistry of an O2S2-macrocycle with copper(I), mercury(II) and palladium(II) ions. CrystEngComm. 2013, 15 (42), 8544-8551.

GHS Hazard and Precautionary Statements

Hazard Statements: H290-H314-H332

May be corrosive to metals. Causes severe skin burns and eye damage. Harmful if inhaled.

Precautionary Statements: P234-P260-P264b-P271-P280-P284-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P390-P501c

Keep only in original container. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
QV0560000

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