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45565 Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer

CAS Number
12354-84-6
Synonyms

Stock No. Size Price ($) Quantity Availability
45565-ME 500mg 140.00
45565-04 2g 438.00
10g Pricing available on request. Click Bulk Quote button and specify size.
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Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer

MDL
MFCD00075435

Chemical Properties

Formula
C20H30Cl4Ir2
Formula Weight
796.67
Storage & Sensitivity
Ambient temperatures.

Applications

Dichloro(pentamethylcyclopentadienyl)iridium(III) dimer is used as a precursor to catalysts for the asymmetric transfer hydrogenation of ketones. It is a catalyst for greener amine synthesis.

Notes

Incompatible with strong oxidizing agents.

Literature References

Lin, Y. J.; Han, Y. F.; Jin, G. X. Synthesis and Structural characterization of half-sandwich iridium macro-metallacycles containing 1,5-dihydroxy-9,10- anthraquinone ligand. J. Organomet. Chem. 2012, 708-709, 31-36.

Han, Y. F.; Lin, Y. J.; Jia, W. G.; Jin, G. X. Synthesis, Characterization, and Electrochemical Properties of Molecular Rectangles of Half-Sandwich Iridium Complexes Containing Bridging Chloranilate Ligands. Organometallics 2008, 27 (16), 4088-4097.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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