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Bis(tri-o-tolylphosphine)palladium(0) is used as a catalyst for palladium-catalyzed cross-coupling reactions, Kumada coupling and Heck coupling. It is also used in the amination and arylation reactions.
Hering, F.; Radius, U. From NHC to Imidazolyl Ligand: Synthesis of Platinum and Palladium Complexes d10-[M (NHC)2](M= Pd, Pt) of the NHC 1, 3-Diisopropylimidazolin-2-ylidene. Organometallics 2015, 34 (13), 3236-3245.
Stambuli, J. P.; Bühl, M.; Hartwig, J. F. Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. J. Am. Chem. Soc. 2002, 124 (32), 9346-9347.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant