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45814 Bis(tri-o-tolylphosphine)palladium(0), Pd 14.9%

CAS Number
69861-71-8
Synonyms

Stock No. Size Price ($) Quantity Availability
45814-MD 250mg 78.40
45814-03 1g 250.00
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Bis(tri-o-tolylphosphine)palladium(0), Pd 14.9%

MDL
MFCD12911908

Chemical Properties

Formula
C42H42P2Pd
Formula Weight
715.16
Form
Crystalline
Melting point
220-225°
Storage & Sensitivity
Air Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Insoluble in water.

Applications

Bis(tri-o-tolylphosphine)palladium(0) is used as a catalyst for palladium-catalyzed cross-coupling reactions, Kumada coupling and Heck coupling. It is also used in the amination and arylation reactions.

Notes

Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

Literature References

Hering, F.; Radius, U. From NHC to Imidazolyl Ligand: Synthesis of Platinum and Palladium Complexes d10-[M (NHC)2](M= Pd, Pt) of the NHC 1, 3-Diisopropylimidazolin-2-ylidene. Organometallics 2015, 34 (13), 3236-3245.

Stambuli, J. P.; Bühl, M.; Hartwig, J. F. Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. J. Am. Chem. Soc. 2002, 124 (32), 9346-9347.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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