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Bis[1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene]palladium(0) is used to prepare palladium(0) catalysts for highly selective cross-coupling reactions especially carbohalogenation reactions.
Bertini, S.; Parkkari, T.; Savinainen, J. R.; Arena, C.; Saccomanni, G.; Saguto, S.; Ligresti, A.; Allarà, M.; Bruno, A.; Marinelli, L.; Marzo, V. D.; Novellino, E.; Manera. C.; Macchia, M. Synthesis, biological activity and molecular modeling of new biphenylic carboxamides as potent and selective CB2 receptor ligands. Eur. J. Med. Chem. 2015, 90, 526-536.
Dai, X.; Chen, Y.; Garrell, S.; Liu, H.; Zhang, L. K.; Palani, A.; Hughes, G.; Nargund, R. Ligand-Dependent site-selective suzuki cross-coupling of 3, 5-dichloropyridazines. J. Org. Chem. 2013, 78 (15), 7758-7763.
Hazard Statements: H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant