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45913 Bis[1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene]palladium(0)

CAS Number
565441-56-7
Synonyms
Pd(Qhos)2

Stock No. Size Price ($) Quantity Availability
45913-MD 250mg 212.00
45913-03 1g 672.00
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Bis[1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene]palladium(0)

MDL
MFCD15071401

Chemical Properties

Formula
C96H94Fe2P2Pd
Formula Weight
1527.86
Form
Crystalline
Storage & Sensitivity
Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Insoluble in water.

Applications

Bis[1,2,3,4,5-pentaphenyl-1'-(di-tert-butylphosphino)ferrocene]palladium(0) is used to prepare palladium(0) catalysts for highly selective cross-coupling reactions especially carbohalogenation reactions.

Notes

Air sensitive. Incompatible with oxidizing agents.

Literature References

Bertini, S.; Parkkari, T.; Savinainen, J. R.; Arena, C.; Saccomanni, G.; Saguto, S.; Ligresti, A.; Allarà, M.; Bruno, A.; Marinelli, L.; Marzo, V. D.; Novellino, E.; Manera. C.; Macchia, M. Synthesis, biological activity and molecular modeling of new biphenylic carboxamides as potent and selective CB2 receptor ligands. Eur. J. Med. Chem. 2015, 90, 526-536.

Dai, X.; Chen, Y.; Garrell, S.; Liu, H.; Zhang, L. K.; Palani, A.; Hughes, G.; Nargund, R. Ligand-Dependent site-selective suzuki cross-coupling of 3, 5-dichloropyridazines. J. Org. Chem. 2013, 78 (15), 7758-7763.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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