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46118 Methylmagnesium chloride, 3M in THF

CAS Number
676-58-4
Synonyms

Stock No. Size Price ($) Quantity Availability
46118-JS 0.25mole 61.70
46118-JU 1mole 164.00
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Methylmagnesium chloride, 3M in THF

MDL
MFCD00000468
EINECS
211-629-7

Chemical Properties

Formula
CH3ClMg
Formula Weight
74.81
Form
Liquid
Flash Point
-17°(1°F)
Density
1.013
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Ambient temperatures.
Solubility
Insoluble in hydrocarbons

Applications

Methylmagnesium chloride is used as a Grignard reagent and an alkylating agent in organic synthesis.

Notes

Store in coo, dry place in tightly closed container. With good ventilation.

Literature References

Kaoru FUJI,; Kiyoshi TANAKA,; Mija AHN,; Maki MIZUCHI.Diastereoselectivity in Addition of Methylmagnesium Halide to Benzoylformate of Chiral 1, 1'-Binaphthalene-2, 2'-diol. Journal name. 1994, 42(4) ,957-959.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H260-H314-H335-H336-H351

Highly flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer.

Precautionary Statements: P201-P202-P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P281-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P335+P334-P363-P370+P378q-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3587199
Hazard Class
4.3
Packing Group
I
Harmonized Tariff Code
2931.90
TSCA
Yes

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