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46332 Allyl(chloro)[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II)

CAS Number
1235509-04-2
Synonyms
PdClAllyl(Amphos)

Stock No. Size Price ($) Quantity Availability
46332-03 1g 251.00
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Allyl(chloro)[di-tert-butyl(4-dimethylaminophenyl)phosphine]palladium(II)

MDL
MFCD25372543

Chemical Properties

Formula
C19H33ClNPPd
Formula Weight
448.32
Form
Solid
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

The derivative of this compound serves as an exceptionally mild and versatile catalyst for Heck reactions of aryl chlorides and bromides. A sterically and electronically diverse array of aryl bromides, as well as activated aryl chlorides, couple with a range of mono- and disubstituted olefins at room temperature, furnishing the arylated product with high E/Z stereoselection.

Notes

Store at room temperature. Incompatible with oxidizing agents.

Literature References

Adam F. Littke.; Gregory C. Fu. A Versatile Catalyst for Heck Reactions of Aryl Chlorides and Aryl Bromides under Mild Conditions. J. Am. Chem. Soc. 2001, 123 (29),6989-7000.

Kohei Endo.; Takahiro Ohkubo.; Takafumi Ishioka.; Takanori Shibata. Cross Coupling between sp3-Carbon and sp3-Carbon Using a Diborylmethane Derivative at Room Temperature.J. Org. Chem. 2012, 77 (10),4826-4831.

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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