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46462 Palladium, 1% on granular carbon, reduced

CAS Number
Synonyms

Stock No. Size Price ($) Quantity Availability
46462-14 25g 108.00
46462-22 100g 379.00
46462-36 500g 1515.00
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Palladium, 1% on granular carbon, reduced

MDL
MFCD00011167

Chemical Properties

Form
3mm (0.13in) Pellets
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

It is used in hydrogenation of aromatic and aliphatic nitro groups; in reductive alkylation/amination; hydrogenation of aromatic carbonyls, olefins, nitriles and as a catalyst in the Suzuki reaction and Stille reaction.

Notes

Palladium on carbon should always be handled under an inert atmosphere (preferably argon) and reaction vessels should be flushed with inert gas before the catalyst is added. Incompatible with acid and oxidizing agents.

Literature References

Dinh, L. N.; Cairns, G. A.; Strickland, R. A.; McLean, W.; Maxwell, R. S. Mechanism and Kinetic Modeling of Hydrogenation in the Organic Getter/Palladium Catalyst/Activated Carbon Systems. J. Phys. Chem. A. 2015, 119, (6), 943-951.

Liu, X.; Zhang, Z.; Yang, Y.; Yin, D.; Su, S.; Lei, D.; Yang, J. Selective hydrogenation of citral to 3,7-dimethyloctanal over activated carbon supported nano-palladium under atmospheric pressure. Chem. Eng. J. 2015, 263, 290-298.

Hazard Statements:

Other References

Harmonized Tariff Code
3815.12
TSCA
Yes

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