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46503 Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), Pd 13.5-15.5%

CAS Number
72287-26-4
Synonyms
[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride

Stock No. Size Price ($) Quantity Availability
46503-03 1g 61.00
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Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), Pd 13.5-15.5%

MDL
MFCD00015757
EINECS
460-040-3

Chemical Properties

Formula
C34H28Cl2FeP2Pd
Formula Weight
731.72
Form
Solid
Melting point
266-283°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in dichloromethane.

Applications

Used as a catalyst for Suzuki and Stile couplings.

Notes

Store away from oxidizing agents.

Literature References

Tamio Hayashi; Mitsuo Konishi; Yuji Kobori; Makoto Kumada; Taiichi Higuchi; Ken Hirotsu. Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II): an effective catalyst for cross-coupling of secondary and primary alkyl Grignard and alkylzinc reagents with organic halides. J. Am. Chem. Soc. 1984, 106 (1), 158-163.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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