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46581 (1,5-Cyclooctadiene)iridium(I) 2,4-pentanedionate

CAS Number
12154-84-6
Synonyms
Acetylacetonato(1,5-cyclooctadiene)iridium(I)
Ir(acac)(cod)

Stock No. Size Price ($) Quantity Availability
46581-03 1g 202.00
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(1,5-Cyclooctadiene)iridium(I) 2,4-pentanedionate

MDL
MFCD08273779

Chemical Properties

Formula
C13H19O2Ir
Formula Weight
399.51
Form
Crystalline solid
Melting point
150-155° dec.
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

It is a umicore precatalysts for asymmetric and cross-coupling catalysis.

Notes

Store in cool dry place. Keep container tightly closed. Keep away from oxidizing agents.

Literature References

Stephanie A. Vierkoetter.; Craig E. Barnes.; Greta L. Garner.; Leslie G. Butler. Olefin Rotation in the Solid State: A 13C, 1H, and 2H NMR Study of Rh(acac)(C2H4)2.J. Am. Chem. Soc. 1994, 116 (16),7445-7446.

H. Vuori.; A. Pasanen.; M. Lindblad.; M. Valden.; M. Veringa Niemelä.; A.O.I. Krause. The effect of iridium precursor on oxide-supported iridium catalysts prepared by atomic layer deposition. Appl. Surf. Sci. 2011, 257 (9),4204-4210.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No
RTECS
NO3615000

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