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46685 Palladium(II) trimethylacetate

CAS Number
106224-36-6
Synonyms
Palladium(II) pivalate
2,2-Dimethylpropionic acid palladium(II) salt

Stock No. Size Price ($) Quantity Availability
46685-03 1g 220.00
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Palladium(II) trimethylacetate

MDL
MFCD16038138

Chemical Properties

Formula
C10H18O4Pd
Formula Weight
308.67
Form
Solid
Melting point
230-232°
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in ethyl acetate, methanol, chloroform, tetrahydrofuran and 1,4-dioxane. Insoluble in water.

Applications

Palladium(II) trimethylacetate is used as a catalyst for aerobic cyclization of acrylic acid with alkenes. It is utilized in the benzylation of heterocycles with benzyl chloride and direct arylation reactions. Furthermore, it is used in regioselective oxidative arene cross-coupling.

Notes

Air and moisture sensitive. Incompatible with strong oxidizing agents.

Literature References

Jones, A. W.; Louillat-Habermeyer, M. L.; Patureau, F. W. Strained Dehydrogenative Ring Closure of Phenylcarbazoles. Adv. Synth. Catal. 2015, 357 (5), 945-949.

Stuart, D. R.; Fagnou, K. The catalytic cross-coupling of unactivated arenes. Science 2007, 316 (5828), 1172-1175.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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