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46780 Dichloro[bis(dicyclohexylphosphino)propane]palladium(II)

CAS Number
1041005-52-0
Synonyms
PdCl2(dcypp)
[Bis(dicyclohexylphosphino)propane]dibromopalladium(II)

Stock No. Size Price ($) Quantity Availability
46780-03 1g 260.00
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Dichloro[bis(dicyclohexylphosphino)propane]palladium(II)

MDL
MFCD14155689

Chemical Properties

Formula
C27H50Cl2P2Pd
Formula Weight
613.97
Form
Crystalline solid
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in dichloromethane and chloroform.

Applications

Dichloro[bis(dicyclohexylphosphino)propane]palladium(II) is used as a catalyst in coupling reactions.

Notes

Incompatible with strong oxidizing agents.

Literature References

Iwasaki, M.; Araki, Y.; Iino, S.; Nishihara, Y. Synthesis of Multisubstituted Triphenylenes and Phenanthrenes by Cascade Reaction of o-Iodobiphenyls or (Z)- β-Halostyrenes with o-Bromobenzyl Alcohols through Two Sequential C-C Bond Formations Catalyzed by a Palladium Complex. J. Org. Chem. 2015, 80 (18), 9247-9263.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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