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46884 1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-µ-hydrotetracarbonyldiruthenium(II), 98%

CAS Number
104439-77-2
Synonyms
Shvo's Catalyst

Stock No. Size Price ($) Quantity Availability
46884-02 0.5g 111.00
46884-04 2g 349.00
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1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-µ-hydrotetracarbonyldiruthenium(II), 98%

MDL
MFCD03840556

Chemical Properties

Formula
C62H42O6Ru2
Formula Weight
1085.15
Form
Crystalline
Melting point
223-227°
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in water and polar organic solvents.

Applications

1-Hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-µ-hydroteracarbonyldiruthenium(II) is widely used in various types of applications in organic synthesis. It is used for hydrogenation of carbonyls, alkenes and imines. It is also used in the alkylation of amines and amination of propargyl alcohols.

Notes

Moisture sensitive. Keep container tightly sealed. Store in cool, dry condition. Protect from humidity and keep away from water. Incompatible with water and oxidizing agents.

Literature References

Zhang, X.; Lu, Z.; Foellmer, L. K.; Williams, T. J. Nitrogen-Based Ligands Accelerate Ammonia Borane Dehydrogenation with the Shvo Catalyst. Organometallics 2015, 34 (15), 3732-3738.

Liu, Q.; Lu, X.; Sund, X.; Zhao, X. Density functional study on the mechanism of direct N-acylation reaction of lactams with aldehydes catalyzed by Shvo's catalyst. Org. Chem. Front. 2015, 2, 961-967.

Other References

Merck
14,8483
Harmonized Tariff Code
2843.90
TSCA
No

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