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46886 Diiodo(p-cymene)ruthenium(II) dimer

CAS Number
90614-07-6
Synonyms
Di-µ-iodobis[(p-cymene)iodoruthenium(II)]

Stock No. Size Price ($) Quantity Availability
46886-03 1g 78.20
46886-06 5g 355.00
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Diiodo(p-cymene)ruthenium(II) dimer

MDL
MFCD08064027

Chemical Properties

Formula
C20H28I4Ru2
Formula Weight
978.20
Form
Crystalline solid
Storage & Sensitivity
Moisture Sensitive. Light Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Insoluble in water.

Applications

Diiodo(p-cymene)ruthenium(II) dimer can be applied as a catalyst for many reactions such as ruthenium-catalyzed hydrogenation, preparation of Walphos-type ferrocenyl-aryl diphosphine ligands, ruthenium-catalyzed synthesis reactions, and enantioselective hydrogenation of ketones and olefins.

Notes

Moisture and light sensitive. Store under inert gas. Incompatible with oxidizing agents, water/ moisture, light.

Literature References

Qing-An Chen; Duo-Sheng Wang; Yong-Gui Zhou; Ying Duan; Hong-Jun Fan; Yan Yang; Zhang Zhang. Convergent asymmetric disproportionation reactions: metal/Brønsted acid relay catalysis for enantioselective reduction of quinoxalines.. Journal of the American Chemical Society. 2011, 133 (16), 6126-6129.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H319-H341-H500

Harmful if swallowed. Causes serious eye irritation. Suspected of causing genetic defects. May form combustible dust concentrations in air

Precautionary Statements: P201-P202-P264b-P270-P280i-P281-P301+P312-P305+P351+P338-P308+P313-P330-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Wear eye/face protection. Use personal protective equipment as required. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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