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46948 Scandium(III) bis(trifluoromethylsulfonyl)imide

CAS Number
176726-07-1
Synonyms
Scandium triflimide
Scandium(III) trifluoromethanesulfonimide

Stock No. Size Price ($) Quantity Availability
46948-MD 250mg 60.70
46948-03 1g 193.00
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Scandium(III) bis(trifluoromethylsulfonyl)imide

MDL
MFCD03427000

Chemical Properties

Formula
C6F18S6O12N3Sc
Formula Weight
885.37
Form
Solid
Melting point
199-204°
Storage & Sensitivity
Moisture Sensitive. Store under Argon. Ambient temperatures.
Solubility
Insoluble in water.

Applications

Scandium(III) bis(trifluoromethylsulfonyl)imide is used as Lewis acid.

Notes

Moisture sensitive. Store away from water/ moisture, oxidizing agents.

Literature References

Mukund P. Sibi; Goran Petrovic. Enantioselective radical reactions: the use of metal triflimides as Lewis acids. Tetrahedron: Asymmetry. 2003, 14 (19), 2879-2882.

Roman Arvai ; Fabien Toulgoat; Bernard R. Langlois; Jean-Yves Sanchez; Maurice Médebielle. A simple access to metallic or onium bistrifluoromethanesulfonimide salts. Tetrahedron. 2009, 65 (27), 5361-5368.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2846.90
TSCA
No

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