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Chromium(II) chloride is used in the condensation of aldehydes with trisubstituted chloroalkenes as well as in the synthesis of a highly active precatalyst for ethylene oligimerization. Further uses of chromium(II) chloride include the conversion of terminal olefins into trans-iodocyclopropanes (in conjunction with iodoform and tetraethyl ethylenediamine) with excellent results; generating bis(indenyl)chromium dimers and other various related products.
Kazuhiko Takai.; Keizo Kimura.; Tooru Kuroda.; Tamejiro Hiyama.; Hitosi Nozaki. Selective grignard-type carbonyl addition of alkenyl halides mediated by chromium(II) chloride. Tetrahedron Lett. 1983, 24 (47),5281-5284.
Hazard Statements: H302-H315-H319-H335
Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant