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47182 Ruthenium(III) chloride, anhydrous, Ru 47.7% min

CAS Number
10049-08-8
Synonyms

Stock No. Size Price ($) Quantity Availability
47182-04 2g 79.00
47182-09 10g 336.00
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Ruthenium(III) chloride, anhydrous, Ru 47.7% min

MDL
MFCD00011208
EINECS
233-167-5

Chemical Properties

Formula
Cl3Ru
Formula Weight
207.43
Form
Powder
Melting point
>500° dec.
Density
3.110
Storage & Sensitivity
Hygroscopic. Ambient temperatures.

Applications

Ruthenium(III) chloride is widely used as a starting material of ruthenium complexes. It acts as a catalyst used in the oxidative cyclization of 1,7-dienes to oxepane diols. It is used in the hydroxylation of tertiary hydrocarbons in combination of periodate or bromate. It is involved as a catalyst in the synthesis of 2,3-pyridinedicarboxylic acid-13C3, 15N, where the unlabelled analog is an inhibitor of glucose synthesis.

Notes

Moisture sensitive. Hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and zinc.

Literature References

Kariuki, P. N.; Madl, C. M.; Martin, J. J.; Upreti, S.; Jones, W. E. Synthesis and bonding of trans-dichlorobis (1, 3-diaminopropane) ruthenium(III) chloride to a self assembled monolayer and its effect on conducting polymer sheet conductivity. Inorg. Chim. Acta 2012, 383, 320-326.

Skunik-Nuckowska, M.; Bacal, P.; Kulesza, P. J. Charge storage and capacitance-type properties of multi-walled carbon nanotubes modified with ruthenium analogue of Prussian Blue. J. Solid State Electrochem. 2015, 19 (9), 2753-2762.

GHS Hazard and Precautionary Statements

Hazard Statements: H290-H302-H314-H335

May be corrosive to metals. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P234-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P390-P501c

Keep only in original container. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,8302
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
VM2650000

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