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47196 Thulium(III) bromide, ultra dry, 99.99% (REO)

CAS Number
14456-51-0
Synonyms

Stock No. Size Price ($) Quantity Availability
47196-03 1g 153.00
47196-06 5g 345.00
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Thulium(III) bromide, ultra dry, 99.99% (REO)

MDL
MFCD00050138
EINECS
238-444-4

Chemical Properties

Formula
TmBr3
Formula Weight
408.66
Form
-10 Mesh Beads, Ampouled under argon
Melting point
952°
Boiling Point
1440°
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Soluble in water.

Applications

Thulium(III) bromide is used for development of advanced ceramic discharge lamps1 and metal halide lamp. Reagent for complexation of lanthanide bromides with aluminum bromide. Reactant for preparation of alkali metal thulium bromides.

Notes

Hygroscopic. Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literature References

Zhi-Chang Wang and Jin Yu. Systematics and anomalies in rare earth/aluminum bromide vapor complexes: thermodynamic properties of the vapor complexes LnAl3Br12 from Ln = Sc to Ln = Lu. Inorganic Chemistry. 2007, 46 (10), 4248-4255.

Shin-ichi Ishiguro.; Kazusuke Kato.; Satoshi Nakasone.; Ryouta Takahashi.; Kazuhiko Ozutsumi. Steric solvent effect on formation thermodynamics and structure of halogeno complexes of lanthanide(III) ions in N,N-dimethylacetamide. J. Chem. Soc., Faraday Trans. 1996, 92 1869-1875.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2846.90
TSCA
Yes

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    Yttrium(III) chloride, anhydrous, 99.9% (REO)
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