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53115 Nickel(II) bromide, anhydrous, 99%

CAS Number
13462-88-9
Synonyms

Stock No. Size Price ($) Quantity Availability
53115-18 50g 82.80
53115-30 250g 363.00
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Nickel(II) bromide, anhydrous, 99%

MDL
MFCD00011141
EINECS
236-665-0

Chemical Properties

Formula
Br2Ni
Formula Weight
218.53
Form
Crystalline
Melting point
963°
Density
5.098^2^7
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Soluble in water, alcohol and ether.

Applications

Nickel(II) bromide is used as a source of the bromide ion. It is an important raw material and intermediate used in synthetic chemistry. Further, it is used as a catalyst in cross-coupling reactions.It is used in the preparation of paramagnetic trans-diaquabis(N,N-diethylethylenediamine) nickel(II) bromide and diamagnetic bis(N,N-diethylethylenediamine)nickel(II) bromide.

Notes

Hygroscopic. Incompatible with strong oxidizing agents, strong acids, bases, alkali metals and alkaline earth metals.

Literature References

Pramanik, M.; Shieh, F. K.; Alshehri, S. M.; Alothman, Z. A.; Wu, K. C. W.; Yamauchi, Y. Template-free synthesis of nanoporous gadolinium phosphonate as a magnetic resonance imaging (MRI) agent. RSC Adv. 2015, 5 (53), 42762-42767.

Rossetto, E.; Nicola, B. P.; de Souza, R. F.; Pergher, S. B. C.; Bernardo-Gusmão, K. Anchoring via covalent binding of beta-diimine-nickel complexes in SBA-15 and its application in catalytic reactions. Appl. Catal., A 2015, 502, 221-229.

GHS Hazard and Precautionary Statements

Hazard Statements: H317-H334-H335-H341-H350i-H360D-H372

May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Suspected of causing genetic defects. May cause cancer by inhalation. May damage the unborn child. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P260-P264b-P270-P271-P272-P280g-P281-P285-P302+P352-P304+P340-P308+P313-P333+P313-P342+P311-P363-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,6502
Hazard Class
9
Packing Group
III
Harmonized Tariff Code
2827.59
TSCA
Yes

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