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71177 Triphenyltin hydroxide

CAS Number
76-87-9
Synonyms
Hydroxytriphenyltin

Stock No. Size Price ($) Quantity Availability
71177-14 25g 31.30
71177-22 100g 108.00
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Triphenyltin hydroxide

MDL
MFCD00013928
EINECS
200-990-6

Chemical Properties

Formula
C18H16OSn
Formula Weight
367.01
Form
Powder
Melting point
122-124°
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in alcohol, toluene

Applications

Reactant involved in transmetalation reactions with Ir clusters. Reactant involved in synthesis of (E)-(Nitrophenyl)propenoic acid organotin(IV) carboxylates with antitumor activity, triorganotin chrysanthemumates for larvicidal studies, polynuclear organotin(IV) carboxylates containing ferrocenyl moieties for antitumor investigation, organotin(IV) aminophenylacrylate complexes, 4-Biphenylcarboxylic acid derivatives for in vitro cytotoxicity studies.

Notes

Keep container tightly closed. Store away from oxidizing agents.

Literature References

B. Kushlefsky.; I. Simmons.; A. Ross. Characterization of Triphenyltin Hydroxide and Bis-(triphenyltin) Oxide. Inorg. Chem. 1963, 2 (1), 187-189.

Charles J. Soderquist.; Donald G. Crosby. Degradation of triphenyltin hydroxide in water. J. Agric. Food Chem. 1980, 28 (1), 111-117.

GHS Hazard and Precautionary Statements

Hazard Statements: H301+H311-H315-H318-H330-H335-H351-H361d-H372

Toxic if swallowed. Toxic in contact with skin. Causes skin irritation. Causes serious eye damage. Fatal if inhaled. May cause respiratory irritation. Suspected of causing cancer. Suspected of damaging the unborn child. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P260-P264b-P270-P271-P281-P284-P301+P310-P302+P352-P304+P340-P305+P351+P338-P308+P313-P310-P312-P330-P332+P313-P361-P363-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. If skin irritation occurs: Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,9745
Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
WH8575000

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