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77137 Titanium(IV) methoxide, 95%

CAS Number
992-92-7
Synonyms
Methyl orthotitanate
Methyl titanate(IV)

Stock No. Size Price ($) Quantity Availability
77137-14 25g 51.90
77137-22 100g 175.00
77137-36 500g 716.00
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Titanium(IV) methoxide, 95%

MDL
MFCD00014883
EINECS
213-596-4

Chemical Properties

Formula
Ti(OCH3)4•(CH3OH)x, x<1
Form
Granular/ lump
Melting point
200-210^o
Boiling Point
243^o/52mm
Flash Point
48°(118°F)
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Slightly soluble in organic solvents.

Applications

Titanium(IV) methoxide is used for the preparation of polyoxotitanates.

Notes

Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides, reducing agents and alkali metals.

Literature References

Buckwalter, D. J.; Dennis, J. M.; Long, T. E. Amide-containing segmented copolymers. Prog. Polym. Sci. 2015, 45, 1-22.

Vinogradov, A. V.; Ermakova, A. V.; Butman, M. F.; Hey-Hawkins, E.; Vinogradov, V. V. A facile sol-gel synthesis of impurity-free nanocrystalline titania. Phys. Chem. Chem. Phys. 2014, 16 (22), 10614-10619.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H302+H312-H315-H318-H335

Flammable solid. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P240-P241-P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.1
Packing Group
III
Harmonized Tariff Code
2905.19
TSCA
Yes

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