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77142 Titanium(IV) ethoxide, TiO2 33% min

CAS Number
3087-36-3
Synonyms
Tetraethyl titanate

Stock No. Size Price ($) Quantity Availability
77142-06 5g 28.00
77142-18 50g 48.00
77142-30 250g 144.00
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Titanium(IV) ethoxide, TiO2 33% min

MDL
MFCD00009071
EINECS
221-410-8

Chemical Properties

Formula
C8H20O4Ti
Formula Weight
228.15
Form
Liquid
Melting point
-40°
Boiling Point
150-152°/10mm
Flash Point
28°(84°F)
Density
1.088
Refractive Index
1.5043
Storage & Sensitivity
Moisture Sensitive. Store under Argon. Ambient temperatures.
Solubility
Soluble in organic solvents. Decomposes in water.

Applications

Titanium(IV) ethoxide is used in organic synthesis and material science. It is involved in the synthesis of anti-perspirants and antifungal agents. Furthermore, it is used to prepare carbon films in association with silicon dioxide. It is also used as a precursor for the synthesis of Ti4+ ions titanium nanoparticles by various methods.

Notes

Moisture sensitive. Hygroscopic. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, water and acids.

Literature References

Durrant, S. F.; da Cruz, N. C.; Rangel, E. C.; de Moraes, M. A. B. Plasma enhanced chemical vapor deposition of titanium(IV) ethoxide-oxygen-helium mixtures. Thin Solid Films 2008, 516 (15), 4940-4945.

Yang, Z.; Wang, B.; Zhang, J.; Cui, H.; Pan, Y.; An, H.; Zhai, J. Factors influencing the photocatalytic activity of rutile TiO2 nanorods with different aspect ratios for dye degradation and Cr(vi) photoreduction. Phys. Chem. Chem. Phys. 2015, 17 (28), 18670-18676.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H319

Flammable liquid and vapour. Causes serious eye irritation.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P264b-P280-P303+P361+P353-P305+P351+P338-P337+P313-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2905.19
TSCA
Yes

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